Effect of In-Situ Synthesized Cerium Oxide Nanoparticles on Oil Recovery Factor In a Glass Micromodel
Pages 3-14
Nafiseh Mehrooz; Reza Gharibshahi; Arezou Jafari; Hamid Delavari; Saeid Sadeghnejad
Abstract Research subject: In situ synthesis of nanoparticles due to greater impact on production mechanisms (such as reducing oil viscosity), uniform distribution of nanoparticles in reservoir fluids, no reduction in formation permeability due to no injection of nanofluids into the reservoir and also economic efficiency is more importance than other nanoparticle synthesis methods which are used in enhanced oil recovery (EOR) processes.
Research approach: In this study, the effect of in-situ synthesized of cerium oxide (CeO2) nanoparticles at low temperature on the oil recovery factor was investigated. For this purpose, water was considered as the based fluid for dispersion of synthesized nanoparticles. Also, in order to study the effect of nanoparticles concentration in the base fluid on the final oil recovery factor, several nanofluids were prepared at different concentrations of 0.01, 0.1, 0.25 and 0.5 wt.%. Finally, the prepared nanofluids were injected at the injection rate of 0.07 ml/h up to 1 PV into the micromodel and the amount of produced oil and the movement of the injected fluid in the porous medium were analyzed.
Main results: The results showed that the synthesized CeO2 nanoparticles in this study have appropriate performance to improve the oil recovery factor. The presence of small amounts of these nanoparticles (concentration of 0.01 wt. %), causes a significant increment in oil recovery factor (about 7%) compared to water injection alone. Also, the oil extraction coefficient increased by increasing the concentration of nanoparticles in the base fluid. So that for nanofluids with concentrations of 0.01, 0.1, 0.25 and 0.5 wt.%, the oil recovery factor were 25%, 38%, 43% and 45%, respectively. However, by increasing the concentration of nanoparticles in the base fluid, from an optimal amount onwards, the probability of particle deposition in the micromodel increased, the effect of nanoparticles on changing the hydrodynamic properties of the injected fluid and oil production mechanisms decreased.
Investigating of Treated Natural Zeolite as a Catalyst Support for Propane Oxidative Dehydrogenation Process
Pages 15-26
Fatemeh Ebrahimi Rad; Jafar Towfighi Darian; Saeed Soltanali
Abstract Research Subject: In recent years, industrial-scale production of propylene based on oxidative dehydrogenation of propane has been of particular importance due to the lack of thermodynamic limitations. In this regard, the use of natural zeolites with high abundance and low price has placed a special position. In this research, perlite natural zeolites were treated with ionic liquid solution and acid, then supported vanadium catalysis were synthesized. Performance of catalysis were investigated in oxidative dehydrogenation of propane to propylene process with a mixed feed of propane and air in a fixed bed quartz reactor under condition of atmospheric pressure and temperature of 500˚C with a flow rate of 40000 h-1 (GHSV).
Research Approach: In this study, natural perlite support as a source of aluminum oxide (Al2O3) and silica (SiO2) was ion exchanged by one molar solution of ammonium nitrate (NH4NO3 1 M). Continuously, to investigate the effect of delamination, different acid molar concentrations of nitric acid (HNO3) equal to 0.75, 1.5, and 2.25 were used and then compared with the just modified ion exchange sample without acid leaching (V/PERLIT-I). Dry vanadium impregnation, as an active metal, was carried out to synthesize 8% wt. catalysts. X-ray diffraction analyzes (XRD), scanning electron microscopy (FE-SEM), and ammonia Temperature-programmed desorption program (NH3-TPD) were used to characterization and evaluate the properties of the catalyst.
Main Result: The results showed that the concentration of acid used affects the conversion and selectivity of the catalysis. In comparison, a significant difference was observed between the performance of V/PERLIT-I sample compared to V/PERLIT-IA samples. The maximum selectivity value for V/PERLIT-IA(2.25) was 74%. According to the results, the treated perlite support with suitable selectivity can be considered in the studies of use as an industrial support.
Investigation of different methods of increasing membrane performance for oxygen/nitrogen separation
Pages 27-54
Saba Raveshiyan; javad karimi-Sabet; Parya Amirabedi
Abstract In recent years, air separation using membranes has received much attention as a cost-effective technology for producing relatively pure streams of nitrogen and oxygen. The results of studies show that the design and fabrication of new polymers with the desired structure for the industrialization of polymer membrane technology in the field of oxygen separation from nitrogen is considered very important. The results obtained from various research works show that polymer membranes made on the basis of aromatic polyimides and PIMs due to high selectivity, suitable mechanical, thermal and chemical properties and also benefiting from different structures due to polymer substitutions are a suitable option for separation of oxygen and nitrogen. Moreover, the membrane modification process can greatly increase the mechanical, chemical and selectivity of the membranes and be an effective way to improve the separation of oxygen from nitrogen. The results indicate that the fabrication of blended membranes has increased the selectivity and permeability of the membranes, and the creation of transverse connections in most cases has increased the selectivity of the membranes. Meanwhile, carbon molecular sieve membranes that are made by thermal decomposition of the polymeric raw material under controlled temperature and pressure conditions due to their properties such as high selectivity and permeability, stability in corrosive environments and applicability at high temperatures are suitable options for separation of oxygen and nitrogen. Also, carefully in the results obtained from various research works, it can be seen that the use of driving force and magnetic particles in the polymer simultaneously improves the permeability and selectivity of membranes. As it is predicted, this method is one of the efficient methods in improving the performance of polymer membranes in the field of oxygen and nitrogen separation.
Crosslinking Poly(ε-caprolactone) with benzoyl peroxide by thermal method for making radiotherapy masks
Pages 55-68
Ali Almasganj; seyyed-abbas mousavi
Abstract Research subject: External radiotherapy is a major method of treating cancer. For just hitting the cancer cells by emitting rays, masks are used to stabilize the patient's body in the right position during the radiotherapy, so that the rays are not emitted to the healthy tissues of the patient's body. Due to the unique properties of these masks, suitable polymeric materials must be used to produce them, which has initially been investigated using a variety of thermoplastic polymers.
Research approach: In the following, polycaprolactone is proposed as the main material for making the mask. Due to its low tensile strength, this material alone is not suitable for the intended use. Therefore, the material was cured with different percentages of benzoyl peroxide (BPO) to increase tensile strength by crosslinking of the polymer. The properties of the cured samples were investigated using the tests of gel content, shape memory, unidirectional tensile strength and, DSC diagrams.
Main results: With increasing BPO, the percentage of gel content and shape memory of the cured samples increased. All cured samples had a high percentage of shape recovery, the highest of which belonged to samples containing 2 and 3% by weight of BPO. By Examining the tensile strength test diagrams, it was observed that by increasing the amount of BPO from 0.5 to 2% by weight in the cured samples, the tensile strength at the breaking point increased to 10 MPa. Shape recovery and tensile strength at the breaking point were 94% and 10 MPa for both cured polycaprolactone samples with 2% by weight of BPO and the Orfit mask, which were very similar in this respect. Finally, a mixture of PCL with 2% by weight of BPO is proposed to make a radiotherapy mask.
Performance assessment of the hybrid nanofluid mixture of iron oxide nanoparticles and graphene nanosheets in the elimination of CO2 from the air, using a venturi scrubber
Pages 69-79
Shadab Shahsavari; aliakbar jamshidi; abbas kazemi; fariborz azizinezhad; farhang farahmand ghavi
Abstract Abstract
Research subject: The combustion of fossil fuels to supply energy produces large amounts of carbon dioxide. Carbon dioxide emissions have led to rising global temperature and many natural disasters, including floods, hurricanes, rising sea levels, and widespread droughts, that threaten ecological systems and human life. Therefore, the uptake and removal of carbon dioxide from sources or the environment play a key role in countering the threat of global warming.
Research approach: In this study, a venturi scrubber was utilized to eliminate CO2 from the air stream on a semi-industrial scale. The effects of different parameters including inlet air flow rate to the venturi scrubber, solvent flow rate, and solvent loss during the scrubbing process were investigated on CO2 absorption by a nanofluid solvent containing iron oxide/water at the presence of tetramethylammonium hydroxide (TMAH) as a surface-active material.
Main results: The surface-active material of TMAH prevents the agglomeration of nanoparticles in the base fluid and stabilizes the fluid. The maximum efficiency of absorption and the highest molar flux of CO2 were achieved when iron oxide nanoparticles were used along with graphene nanosheets with the ratios of iron oxide nanoparticles (25%) and graphene nanosheets (75%) at the presence of TMAH surface-active material due to their nature. The reason is the better agitation (of the solution) by iron oxide nanoparticles that results in an increased displacement of graphene nanosheets. The random Brownian movements of nanoparticles create micron size eddies that increase mass transfer at the gas-liquid interface. In addition, molar flux and CO2 gas absorption efficiency decreased by increasing the concentration of nanoparticles.
Keywords: Hybrid nanofluid; Venturi scrubber; Gas absorption; Iron oxide nanoparticles; Graphene nanosheets
Photocatalytic Removal of Metribuzin Using Titanium Dioxide/Silver Nanocomposite
Pages 81-95
Shahin Heydari Orojlou; Saadat Rastegarzadeh; Behrooz Zargar
Abstract Research subject: In the present study, titanium dioxide/silver nanocomposites (TiO2/Ag) were synthesized by sol-gel method and their performance for photocatalytic removal of metribuzin was compared with commercial TiO2 catalysts P25 Degussa.
Research approach: The synthesized nanocomposites were evaluated using X-ray diffraction spectroscopy (XRD), field emission scanning electron microscopy (FESEM), and energy dispersive X-ray analysis (EDX). The effect of operating parameters including reaction time (0-240 minutes), pH (9-4), catalyst dose (0.005-0.015 g), temperature (10-60 ºC), visible light and UV light radiation, concentration Initial metribuzin (10-25 mg/L), the catalyst effect in the dark, and the amount of silver in TiO2/Ag nanocomposites (0.10-7% by weight) were investigated on the photocatalytic removal of metribuzin from artificial and real aqueous solutions.
Main results: Laboratory investigations showed that TiO2/Ag nanocomposite containing 10% by weight of silver, reaction time of 120 minutes, pH equal to 6, catalyst mass of 0.013 g, and initial concentration of 10 mg/L metribuzin are the best properties to maximize the removal of metribuzin in the presence of UV light. The obtained results showed that the synthesized TiO2/Ag nanocomposite has a higher potential in the degradation of herbicides compared to the commercial TiO2 nano-catalyst. In addition, the proposed method was used to remove metribuzin injected into the water of the Karun and Zohreh rivers and the wastewater of the sugarcane factory under optimal conditions, and successful results were obtained. Also, the results of using and regenerating the titanium dioxide/silver catalyst three times to remove metribuzin show the high efficiency of this photocatalyst in removing metribuzin from water samples. Comparing the methods available in the literature for the removal of metribuzin with the present method showed that the proposed method is better or comparable to the reported methods.