Thermal properties improvement of multilayer super insulators based on novolac aerogel

Author

Department of Polymer, Faculty of chemical engineering, Tarbiat Modares University, Tehran, Iran

Abstract
In human-made materials, aerogels have the least thermal conduction coefficient. The least thermal conduction, which aerogels can have, is equivalent to air conduction, about 0.021W/mK. In some applications, lowest conductions is to be needed. In this study, novolac aerogles are used as spacer, for designing and making multilayer super insulators with aluminum foil reflective layers. The performance of these insulators, are extremely depends on density, porosity and the size of pores in aerogel and number of layers in the overall thickness of insulator. In this study, for decreasing effective thermal conduction of multilayer insulations, tow parameters of density of aerogel and ratio of number of layers to thickness of insulator (layer density), are examined in 25 ˚C to 200 ˚C boundary conditions. First, by assessment of aerogel novolac density effect on thermal conduction, aerogel with density of 0.076 g/cm3 was chosen as the best spacer. In the next part, ratio of 25 layer per centimeter of thickness was chosen as the best layer density. Finally, by making multilayer super insulators, based on this results, an insulator with 5×10-4W/mK effective thermal conductivity was obtaind without evacuation of spacer.

Keywords

Subjects


1- Hedayat A., Hastings A. and Brown T., Analytical Modeling of Variable Density Multilayer Insulation for Cryogenic Storage., NASA/TM–2004–213175.
2- Spinnler M., Winter E.F. and Viskanta R., Studies on High-Temperature Multilayer Thermal Insulations, International Journal of Heat and Mass Transfer, 47, 1305–1312,2004.
3- Bi C., Tang G.H., Hu Z.J., Yang H.L. and Li J.N., Coupling Model for Heat Transfer Between Solid and Gas Phases in Aerogel and Experimental Investigation, International Journal of Heat and Mass Transfer,79, 126-136, 2014.
4- Naseri I., Kazemi A., Bahramian AR. and Kashani M.R., Preparation of organic and carbon xerogels using high-temperature–pressure sol–gel polymerization, Materials & Design 61, 35-40, 2014.
5- Pirard R., Blacher S., Brouers F. and Pirard J. P., Interpretation of Mercury Porosimetry Applied to Aerogels, Journal of Material Research, 10,2114–2119, 1995.
6- Ruben G. C. and Pekala R. W., High-Resolution Transmission Electron Microscopy of the Nanostructure of Melamine-Formaldehyde Aerogels, Journal of Non-Crystal Solids,186,219–231, 1995.
7- Pirard R. and Pirard J.-P., Mercury Porosimetry Applied to Precipitated Silica, Stud. Surface Science Catalyst, 128, 603–611, 2000.
8- Alié C., Pirard R., and Pirard J.-P., Mercury Porosimetry: Applicability of the Buckling–Intrusion Mechanism to Low-Density Xerogels, Journal of Non-Crystal Solids,292,138–149, 2001.
9- Pirard R., Sahouli B., Blacher S., and Pirard J.-P., Sequentially Compressive and Intrusive Mechanisms in Mercury Porosimetry of Carbon Blacks, Journal of Colloid Interface Sci,217, 216–217, 1999.
10- Pirard R., Rigacci A., Marechal J. C., Quenard D., Chevalier B., Achard P., and Pirard J.-P., Characterization of Hyperporous Polyurethane-Based Gels by Non-Intrusive Mercury Porosimetry,Polymer44 , 4881–4887, 2003.
11- Bahramian A.R. and Kokabi M., Ablation Mechanism of Polymer Layered Silicate Nanocomposite Heat Shield,Journal of Hazardous Materials 166, 445-454,2009.
12- Johnson W.L., Optimization of Layer Densities for Spacecraft Multilayered Insulation Systems, Cryogenics Test Laboratory, Kennedy Space Center,4865-4867, 2009.
13- Can H. and Yue Z., Calculation of High-temperature Insulation Parameters and Heat Transfer Behaviors of Multilayer Insulation by Inverse Problems Method, Chinese Journal of Aeronautics ,27,791-796, 2014.
14- Ji T., Zhang R., Sunden B. and Xie G., Investigation on thermal Performance of High Temperature Multilayer Insulations for Hypersonic Vehicles under Aerodynamic Heating Condition, Applied Thermal Engineering 70, 957-965,2014.